Thermodynamics Foundations and Applications 1st edition by Elias Gyftopoulos, Gian Paolo Beretta 9780486135182 0486135187

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ISBN 10: 0486135187
ISBN 13: 9780486135182 
Author: Elias P. Gyftopoulos; Gian Paolo Beretta 

Thermodynamics Foundations and Applications 1st Table of contents:

1 How to Study with This Book
1.1 Modeling Physical Phenomena
1.2 Accounting and Balances
1.3 Energy and Entropy Balances
1.4 Applications of Energy and Entropy Balances
1.5 Problem Solving
1.6 Four Courses of Study

2 Kinematics and Dynamics
2.1 Systems
2.2 Properties and States
2.3 Motions
2.3.1 Spontaneous Changes of State
2.3.2 Induced Changes of State

3 Energy
3.1 Weight Process
3.2 First Law
3.3 Uniqueness of Values of Mg
3.4 Definition of Property Energy
3.5 Additive Properties
3.6 Additivity of Energy
3.7 Conservation of Energy
3.8 Energy Balance
3.9 Energy Transfer in a Weight Process
3.10 Impossibility of Perpetual-Motion Machines of the First Kind
3.11 Absolute Energy and Special Relativity
3.12 Mass Balance
3.13 Comment

4 Stability of Equilibrium
4.1 Types of States
4.1.1 Unsteady State
4.1.2 Steady State
4.1.3 Nonequilibrium State
4.1.4 Equilibrium State
4.1.5 Unstable Equilibrium State
4.1.6 Metastable Equilibrium State
4.1.7 Stable Equilibrium State
4.2 Reversible and Irreversible Processes
4.3 The Problem of Stability
4.4 Second Law
4.5 Impossibility of Perpetual-Motion Machines of the Second Kind
4.6 Historical Statements of the Second Law
4.7 Comment

5 Adiabatic Availability
5.1 A Class of Weight Processes
5.2 Definition of Property Adiabatic Availability
5.3 Features of Adiabatic Availability
5.3.1 Domain of Definition
5.3.2 Physical Meaning
5.3.3 Nonnegativity
5.3.4 Upper Bound
5.3.5 Changes in Reversible Weight Processes
5.3.6 Changes in Irreversible Weight Processes
5.3.7 Criterion for Reversibility
5.3.8 Lack of Additivity
5.4 Proof of Relations (5.11) and (5.12)
5.5 Generalized Adiabatic Availability
5.6 Features of Generalized Adiabatic Availability
5.6.1 Physical Meaning
5.6.2 Positive and Negative Values
5.6.3 Changes in Reversible Weight Processes
5.6.4 Changes in Irreversible Weight Processes
5.6.5 Criterion for Reversibility
5.7 Adiabatic Availability of a Weight
5.8 Comment

6 Available Energy
6.1 Subsystems and Composite Systems
6.2 Mutual Stable Equilibrium
6.3 Reservoirs
6.4 Weight Processes of a System and a Reservoir
6.5 Definition of Property Available Energy
6.6 Features of Available Energy
6.6.1 Domain of Definition
6.6.2 Physical Meaning
6.6.3 Lower Bound
6.6.4 Changes in Reversible Weight Processes
6.6.5 Changes in Irreversible Weight Processes
6.6.6 Criterion for Reversibility
6.7 Additivity of Available Energy
6.8 Generalized Available Energy
6.9 Features of Generalized Available Energy
6.9.1 Physical Meaning
6.9.2 Positive and Negative Values
6.9.3 Changes in Reversible Weight Processes
6.9.4 Changes in Irreversible Weight Processes
6.9.5 Criterion for Reversibility
6.9.6 Additivity

7 Entropy
7.1 Definition of Property Entropy
7.2 Features of Entropy
7.2.1 Domain of Definition
7.2.2 Additivity
7.2.3 Changes in Reversible Weight Processes
7.2.4 Changes in Irreversible Weight Processes
7.2.5 Principle of Nondecrease of Entropy
7.3 Entropy Balance
7.4 Definition of Constant
7.5 Dimensions and Units of Entropy

8 Stable-Equilibrium-State Principle
8.1 State Principle
8.2 Criteria for Stable Equilibrium States
8.3 The Fundamental Relation

9 Temperature
9.1 A Necessary Condition for Mutual Stable Equilibrium
9.2 Definition of Absolute Temperature
9.3 Positivity of Temperature
9.4 Concavity of the Fundamental Relation with Respect to Energy
9.5 Convexity of the Energy Relation with Respect to Entropy
9.6 Temperature as an Escaping Tendency for Energy and Entropy
9.7 Temperature of a Reservoir
9.8 Absolute Entropy
9.9 Third Law
9.10 Relative Temperatures
9.11 Available Energy in Terms of Energy and Entropy
9.12 Adiabatic Availability in Terms of Energy and Entropy

10 Total Potentials
10.1 Additional Necessary Conditions for Mutual Stable Equilibrium
10.2 Total Potential of a Constituent
10.3 Total Potential as an Escaping Tendency of a Constituent
10.4 Reservoirs with Variable Amounts of Constituents

11 Pressure
11.1 Further Necessary Conditions for Mutual Stable Equilibrium
11.2 Pressure
11.3 Pressure as a Capturing Tendency for Volume
11.4 Reservoirs with Variable Amounts of Constituents and Volume
11.5 Partial Mutual Stable Equilibrium

12 Work and Heat
12.1 Work
12.2 A Nonwork Interaction
12.3 Heat
12.4 Work and Heat Only
12.5 Inequality of Clausius

13 Energy versus Entropy Graphs
13.1 Energy versus Entropy Plane
13.2 Zero-Entropy Line
13.3 Ground-Energy States
13.4 The Fundamental Relation
13.5 Perpetual-Motion Machine of the Second Kind
13.6 Equilibrium Thermodynamics
13.7 Adiabatic Availability
13.8 Work in an Adiabatic Process
13.9 Generalized Adiabatic Availability
13.10 Available Energy
13.11 Generalized Available Energy
13.12 Work Interactions
13.13 Heat Interactions
13.14 Nonwork Interactions
13.15 Optimum Changes in Available Energy
13.16 Effects of Irreversibility on the Capacity to Do Work
13.17 Third Law
13.18 Negative Temperatures

14 Summary of Basic Concepts
14.1 Systems, Properties, and States
14.2 Changes of State in Time
14.3 Energy and Energy Balance
14.4 Types of States
14.5 Adiabatic Availability
14.6 Available Energy
14.7 Entropy and Entropy Balance
14.8 Stable Equilibrium States
14.9 Temperature
14.9.1 Temperature of a Reservoir
14.9.2 Relative Temperatures
14.10 Total Potentials
14.11 Pressure
14.11.1 First-Order Taylor Series Expansions
14.11.2 Energy Relation of a Reservoir
14.12 Work and Heat Interactions
14.13 Energy versus Entropy Graphs
14.13.1 Zero-Entropy Line
14.13.2 Lowest-Energy States
14.13.3 The Fundamental Relation
14.13.4 Perpetual-Motion Machine of the Second Kind
14.13.5 Adiabatic Availability
14.13.6 Work in an Adiabatic Process
14.13.7 Available Energy
14.13.8 Work Interactions
14.13.9 Heat Interactions

15 Heat Engines
15.1 Definition of a Heat Engine
15.2 Heat Pumps and Refrigeration Units

16 Systems with Volume as the Only Parameter
16.1 General Remarks
16.2 Independent Properties
16.3 Characteristic Functions
16.4 Maxwell Relations
16.5 Heat and Work interactions
16.5.1 Constant-Volume Processes
16.5.2 Constant-Pressure Processes
16.5.3 Constant-Temperature Processes
16.5.4 Constant-Entropy Processes
16.6 Comment

17 Simple Systems
17.1 Definition of a Simple System
17.2 Implications of Partitioning
17.3 Gibbs, Euler, and Gibbs-Duhem Relations
17.4 Extensive and Intensive Properties
17.5 Dependences of Intensive Properties
17.6 Convexity of Specific Energy
17.7 Gibbs Free Energy
17.8 Partial Properties

18 Phase Rule
18.1 Homogeneous and Heterogeneous States
18.2 Phases
18.3 Gibbs Phase Rule

19 Thermophysical Properties of Pure Substances
19.1 Specific Properties
19.2 Molecular Weight
19.3 Experimental Results
19.4 Specific Latent Heats
19.5 Two-Phase Mixtures
19.6 Tables and Charts of Properties
19.7 Specific Heats
19.8 Equation of State
19.9 Coefficients of Isothermal Compressibility and Isobaric Expansion
19.10 Speed of Sound

20 Ideal Gases, Liquids, and Solids
20.1 Ideal-Gas Behavior
20.2 Perfect-Gas Model
20.3 Specific Heat and Molecular Structure
20.4 Ideal Incompressible Behavior
20.5 Fugacity and Activity
20.6 Effect of Pressure on the Fugacity of a Liquid

21 Equations of State
21.1 Compressibility Factor
21.2 Van der Waals Equation
21.3 Dieterici Equation
21.4 Virial Equations
21.5 Beattie-Bridgeman Equation
21.6 Benedict-Webb-Rubin Equation
21.7 Principle of Corresponding States

22 Bulk Flow
22.1 Bulk-Flow States
22.2 Bulk-Flow Interactions

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