Fundamentals of Electrochemistry 2nd Edition by Vladimir Bagotsky ISBN 9780471700586 047170058X

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ISBN 10: 047170058X
ISBN 13: 9780471700586
Author: Vladimir Bagotsky

Fundamentals of Electrochemistry provides the basic outline of most topics of theoretical and applied electrochemistry for students not yet familiar with this field, as well as an outline of recent and advanced developments in electrochemistry for people who are already dealing with electrochemical problems.

The content of this edition is arranged so that all basic information is contained in the first part of the book, which is now rewritten and simplified in order to make it more accessible and used as a textbook for undergraduate students. More advanced topics, of interest for postgraduate levels, come in the subsequent parts.

This updated second edition focuses on experimental techniques, including a comprehensive chapter on physical methods for the investigation of electrode surfaces. New chapters deal with recent trends in electrochemistry, including nano- and micro-electrochemistry, solid-state electrochemistry, and electrocatalysis. In addition, the authors take into account the worldwide renewal of interest for the problem of fuel cells and include chapters on batteries, fuel cells, and double layer capacitors.

Fundamentals of Electrochemistry 2nd Edition Table of contents:

Chapter 1: Introduction to Electrochemistry

• Definition and Scope of Electrochemistry
• Historical Background and Key Discoveries
• Fundamental Concepts in Electrochemistry
• Applications of Electrochemical Processes

Chapter 2: The Thermodynamics of Electrochemical Reactions

• First and Second Laws of Thermodynamics in Electrochemistry
• Gibbs Free Energy and Electrochemical Reactions
• Nernst Equation and Equilibrium Potentials
• Electrochemical Cells and Their Thermodynamic Descriptions

Chapter 3: Electrode Potentials and Reactions

• Electrode Potential and the Standard Hydrogen Electrode
• Measurement of Electrode Potentials
• Half-Reactions and the Concept of Electrode Potentials
• The Electrochemical Series and Its Applications

Chapter 4: The Kinetics of Electrochemical Reactions

• Activation Energy and Reaction Rates in Electrochemistry
• Butler-Volmer Equation for Electrode Reactions
• Overpotentials and Their Impact on Electrochemical Kinetics
• Diffusion and Mass Transport in Electrochemical Reactions

Chapter 5: Electrochemical Cells and Their Operation

• Galvanic Cells: Principles and Applications
• Concentration Cells and Electrochemical Potentials
• Fuel Cells and Batteries
• Electrochemical Impedance and Performance Characterization

Chapter 6: Electrolysis and Electrochemical Reactions

• The Process of Electrolysis
• Faraday’s Laws of Electrolysis
• Applications of Electrolysis: Electroplating, Electrorefining
• Industrial Applications of Electrolysis

Chapter 7: Ionic Conductance and Electrolyte Solutions

• Conductance of Electrolyte Solutions
• The Debye-Hückel Theory and Ionic Activity
• Transport Numbers and Conductivity in Solutions
• The Effect of Concentration on Electrolyte Properties

Chapter 8: Electrochemical Techniques and Measurements

• Potentiometry and Voltammetry
• Chronoamperometry and Chronopotentiometry
• Electrochemical Impedance Spectroscopy
• Surface Analysis Techniques in Electrochemistry

Chapter 9: Corrosion and Its Prevention

• Basic Principles of Corrosion
• Electrochemical Nature of Corrosion Reactions
• Theories of Corrosion (Galvanic, Concentration Cells)
• Methods of Corrosion Protection: Coatings, Cathodic Protection

Chapter 10: Electrochemical Energy Storage and Conversion

• Principles of Energy Storage in Batteries
• Primary and Secondary Cells: Design and Function
• Supercapacitors and Electrochemical Capacitors
• Redox Flow Batteries and Their Applications

Chapter 11: Electrochemical Synthesis and Nanotechnology

• Electrochemical Synthesis of Organic and Inorganic Compounds
• Electrochemical Deposition and Nanomaterials
• Nanostructures in Electrochemistry
• Electrochemical Approaches to Nanofabrication

Chapter 12: Electrochemical Sensors and Analytical Applications

• Principles of Electrochemical Sensing
• Development of Electrochemical Biosensors
• Applications in Environmental and Medical Analysis
• Chemical Sensors in Industry

Chapter 13: Fuel Cells and Alternative Energy Sources

• Fundamentals of Fuel Cell Technology
• Hydrogen Fuel Cells: Working Principles and Applications
• Methanol and Solid Oxide Fuel Cells
• Electrochemical Conversion of Solar Energy

Chapter 14: Environmental and Industrial Applications of Electrochemistry

• Electrochemical Approaches to Environmental Protection
• Electrochemical Waste Treatment and Remediation
• Electrochemical Synthesis in Industrial Chemistry
• Electrochemical Process Engineering and Design

Chapter 15: Advanced Topics in Electrochemistry

• Non-Equilibrium Thermodynamics in Electrochemistry
• Electrochemical Processes in Biological Systems
• Electrochemical Microdevices and Microsystems
• Future Directions in Electrochemical Research

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